Authors
Abstract
In this study, tungsten oxide and vanadium oxide electrochromic thin films were placed in vacuum and in a thickness of 200 nm on a transparent conductive substrate of SnO2:F using the physical method of thermal evaporation. Then they were studied for the optical characteristics in the wavelength range from 400 to 700 nm and for their electrical potentials in the range form +1.5 to -1.5 volts. The films were post heated in order to assess changes in energy gap with temperature, at temperatures120 , 300 and 500°C. Refractive and extinction coefficients and the transition type of films in the visible light range and in the thickness of 200 nm were determined and measured. X-ray diffraction pattern and SEM images and cyclic Voltammetry of layers were also studied. The results of this study due to the deposition of layers, the layer thickness selected, the type of substrate, the range of annealing temperatures and selected electrolyte were in full compliance with the works of other researchers [1,2,3]. Therefore, these layers with features such as crystal structure, refractive and even extinction coefficients in the range of visible light, the appropriate response of chromic switch in the replication potential, good adhesion to the substrate, and the high amount of optical transmition and so on, prove useful to be used in an electrochromic device
Keywords
2. R Solarska, B D Alexander, and J Augustynski, Comptes Rendus Chimie 9 (2006) 301.
3. G J Fang, K-L Yao, and Z-L Liu, Thin Solid Films 394 (2001) 63.
4. J Livage, D Ganguli, Solar Energy Materials & Solar Cells 60 (2000) 201.
5. C M Lampert, C G Granqvist (Eds), “Large-area Chromogenics: Materials and Devices for Trancmittance Control”, SPIE Optical Engineering Press, Washington (1988).
6. O Schilling and K Colbow, Sens. Actuators B 21 (1994) 151.
7. D Wruck, S Ramamurthi and M Rubin, Thin Solid Films 182 (1989) 79.
8. M U Qadria, M Cinta Pujola, J Ferré-Borrullb, E Llobet, M Aguilóa, and F Díaz; Procedia Engineering 25 (2011) 260.
9. H Hirashima, M Ide, and T Yoshida, J. Non-Cryst. Solids 86 (1986) 327.
10. F Nava, O Bisi, P Psaras, H Takai, and K N Tu, Thin Solid Films 140 (1986) 167 .
11. Wen-Jing Li and Z-W Fu, Applied Surface Science 256, 8 (2010) 2447.
12. C Navonea, S Tintignaca, J P Pereira-Ramosa, R Baddour-Hadjeana, and R Salot; Solid State Ionics 192, 1 (2011) 343.
13. R Sivakumar, A Moses Ezhil Raj, B Subramanian, M Jayachandran, D C Trivedi, and C Sanjeeviraja, Materials Research Bulletin 39 (2004) 1479.
14. A Subrahmanyam, and A Karuppasamy, Solar Energy Materials and Solar Cells 91, 4 (2007) 266.
15. c, C Mathieu; Catalysis Today 113, 3– 4 (2006) 230.
16. C G Granquist, “Handbook of Electrochromic Materials”, Elsevier, Amsterdam (1995).
17. S M A Durrnia, E E Khawaja, M A Salimb, M F Al-Kuhailib, and Al Shukri, Solar Energy Materials & Solar Cells 71 (2002) 313.
18. L Ottaviano, A Pennisi, F Simone, and A M Salvi, Optical Materials 27 (2004) 307.
19. P S Patil, S B Nikam, and L D Kadam, Materials Chemistry and Physics 69 (2001) 77.
20. T Nishide and F Mizukami, Thin Solid Films 259 (1995) 212.
21. E E Khawaja, S M A Durrani, and M A Daus, Journal of Physics: Condensed Matter 9 (1997) 9381.
22. Y B Saddeek and K A Aly, Materials Chemistry and Physics, In Press.
23. A Kumar, P Singh, N Kulkarni, and D Kaur, Thin Solid Films 516 (2008) 912
25. A D McNaught, A Wilkinson, IUPAC, “Compendium of Chemical Terminology”, Blackwell Scientific Publication, Oxford, UK (1997).
26. B D Cullity, “Elements of X-Ray Diffraction”, Addison-Wesley Publishing (1978).
27. K J Patela, C J Panchala, M S Desaia, and P K Mehta; Materials Chemistry and Physics 124, 1 (2010) 884.
28. S S Kalagia, S S Malib, D S Dalavib, A I Inamdarc, H Imc, and P S Patil, Electrochimica Acta 85 (2012) 501.
29. I Quinzeni, S Ferrari, E Quartarone, and P Mustarelli, Journal of Power Sources 196, 23 (2011) 10228.
30. C G Granqvist, Sol. Energy Mater. Sol. Cells 60 (2000) 201.
31. S R Bathe, and P S Patil, Sol. Energy Mater. Sol. Cells 91 (2007) 1097.
32. J Arakaki, R Reyes, M Horn, and W Estrada, Sol. Energy Mater. Sol. Cells 37 (1995) 33.
33. R Deshpande et al., Solid State Ionics 178 (2007) 895.
34. F L Souza, M A Aegerter, and E R Leite, Electrochimica Acta 53, 4 (2007) 1635