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Abstract
Here we study the rotational structure of CF4 molecule for ground state n 4 mode, fine structure step by using J. Moret-Bailly theory. First the calculated spectra are normalized to the experimentally measured spectra, for calculating the centrifugal and coriolis constants up to the third approximation, D =-3.18 ´ 10-3 cm-1, (4) x = 1.33 ´ 10-1 cm-1. Then the rotational energies are calculated for J £ 6.
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